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- Title
Investigation of Ion-Molecular Reactions of Nucleogenic Phenyl Cations with 1,4-Diazine Derivatives.
- Authors
Shchepina, N.; Avrorin, V.; Badun, G.; Vasyanin, A.; Shurov, S.; Agafonova, I.
- Abstract
The use of nuclear-chemical synthesis, based on the generation of free nucleogenic phenyl cations, allowed for the direct phenylation of the nitrogen atom in 1,4-diazines. The presence of two methyl substituents in the quinoxaline substrate leads to a marked increase of diazine salt radiochemical yield. On the basis of quantum-chemical calculations the possibility of synthesizing 2,3-dimethyl-1,4-di-phenylquinoxalinium dication is proposed.
- Publication
Chemistry of Heterocyclic Compounds, 2015, Vol 50, Issue 11, p1595
- ISSN
0009-3122
- Publication type
Academic Journal
- DOI
10.1007/s10593-014-1629-6