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- Title
Synthesis, structure, and properties of nitrilo-tris(methylenephosphonato)-triaquairon(II) {Fe[µ-NH(CHPOH)](HO)}, as an ingredient of anticorrosive protective coatings on the steel surface.
- Authors
Somov, N.; Chausov, F.; Zakirova, R.; Shumilova, M.; Aleksandrov, V.; Petrov, V.
- Abstract
A new non-electrolyte complex of iron(II), {Fe[μ-NH(CHPOH)](HO)}, has been synthesized and investigated. The crystallographic characteristics of the complex are as follows: sp. gr. P2, Z = 4, a = 9.2619(3) Å, b = 16.0548(3) Å, c = 9.7570(3) Å, and β = 115.685(4)°. The iron atom is octahedrally coordinated by the three phosphonate oxygen atoms and three water molecules in the meridional configuration. The complex has a coordination polymer structure; each Fe atom closes the eight-membered chelating cycle Fe-O-P-C-N-C-P-O, and one of the phosphorus atoms of this cycle is bound with an iron atom of a neighboring structural unit.
- Publication
Crystallography Reports, 2015, Vol 60, Issue 6, p853
- ISSN
1063-7745
- Publication type
Academic Journal
- DOI
10.1134/S1063774515060334