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- Title
Amberlyst-15 in organic synthesis.
- Authors
Pal, Rammohan; Sarkar, Taradas; Khasnobis, Shampa
- Abstract
Commercially available Amberlyst-15 has played an important role in organic synthesis. This review summarizes the versatile synthetic applications of Amberlyst-15 in different chemical transformations. Reactions include esterification, transesterification, Michael addition, aza- Michael addition, Prins cyclization, Friedel-Crafts alkylation, acylation, metal free hydroarylation, hydroalkylation, halogenation, protection of carbonyls, amines, deprotection of acetals, acetates, Boc-protected amines, cleavage of epoxides, crossed-aldol condensation, synthesis of quinolines, pyrazolines, indolinones, acridines, calix[4]pyrroles, xanthenes, coumarins, benzopyrans theaspirane, furans, and substituted phosphonates. Applications of this catalyst allow mild and highly selective transformations and synthesis in a facile and environmentally friendly manner. The catalysts can be regenerated and recycled.
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2012, p570
- ISSN
1551-7004
- Publication type
Academic Journal