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- Title
ECO-FRIENDLY SYNTHESIS OF SILVER NANOPARTRICLES USING Gazania rigens AND EVALUATION OF ACTIVITIES.
- Authors
Shahzadi, Tayyaba; Kanwal, Amina; Jabeen, Hifzah; Riaz, Tauheeda; Zaib, Maria
- Abstract
The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis of stable AgNPs. Average size of AgNPs was calculated from XRD spectra as 31.35 nm. SEM and EDX spectra confirmed the synthesis of spherical shaped AgNPs. FTIR spectra showed that different functional groups were present in aqueous extract of plant which acted as reducing agents in the formation of stable silver nanoparticles. The value of DPPH radical inhibition by AgNPs was 75.45±1.12% at 1000 µg/mL concentration revealing its moderate antioxidant activity. Synthesized AgNPs showed good total phenolic contents (262.60±1.2 mg/g GAE) as well as good total antioxidant activity (1.11±0.07). Then the synthesized AgNPs were used as catalyst for the removal of toxic organic dyes i.e methylene blue (MB) and congo red (CR). Various factors like temperature, pH, adsorbent dosage, dye concentration and contact time were examined and optimized for maximum removal of dyes. Thermodynamic factors like enthalpy (ΔH°), Gibb’s free energy (ΔG°), and entropy (ΔS°) of the system were also determined. Kinetics of the system was studied with the help of Lagergren’s model. Adsorption parameters were also calculated using Langmuir and Freundlich, isotherm models
- Publication
Environmental Engineering & Management Journal (EEMJ), 2021, Vol 20, Issue 1, p43
- ISSN
1582-9596
- Publication type
Academic Journal