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- Title
Practical F/Δ-D transformation in the prostaglandin series. synthesis of methyl (±)-(5Z,12 E,14 E)-9α-acetoxy- 16-(3-chlorophenoxy)-15-deoxy-11-oxo-17,18,19,20-tetranorprosta- 5,12,14-trienoate from cloprostenol.
- Authors
Vostrikov, N.; Lobko, I.; Spirikhin, L.; Miftakhov, M.
- Abstract
Methyl (±)-(5 Z,12 E,14 E)-9α-acetoxy-16-(3-chlorophenoxy)-15-deoxy-11-oxo-17,18,19,20-tetranorprosta- 5,12,14-trienoate was synthesized via selective protection/deprotection of the hydroxy groups in cloprostenol methyl ester, followed by oxidation of the C-OH group and DBU-promoted elimination of the 9-acetoxy group.
- Publication
Russian Journal of Organic Chemistry, 2016, Vol 52, Issue 12, p1765
- ISSN
1070-4280
- Publication type
Academic Journal
- DOI
10.1134/S1070428016120095