Your institution may have access to this item. Find your institution then sign in to continue.
Title
Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes.
Authors
Alazet, Sébastien; Zimmer, Luc; Billard, Thierry
Abstract
Pin the tail on the alkyne: CF3S‐ or CF3CF2S‐alkynes can be simply and quickly obtained by mixing terminal alkynes with a trifluoromethanesulfenamide reagent. The reaction uses easy‐to‐handle reagents, and functions under mild conditions without activation by transition metals.
Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 41, p10814